this is between chapter 32 and 35
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His attraction to Estella has never waivered from the first time he met her. Part of the attraction here is that he uncovers her mysterious past - her adoption by Miss Havisham and her rather low class birth parents. He might very well think he could "save" her from her parents Molly and Provis; Jaggers tries as hard as possible to keep Estella mysterious and as a lawyer would, reveals as little as possible.